I leave them in there for 10 minutes or so, but I have had parts in there for over an hour with no problems that I could see.
Vinagar is very mild so should not be a problem if you leave it soaking for a while. Watch out with copper, that is much softer, I don't know any rules for that. You can always try a run with the frame the parts are mounted to to see if there are problems.
I remember an other technique I use sometims, works also with large items. I have a fibre-glass scratch pen that is very usefull for both cleaning and preparing the surface for glue.
I do not use it now, need to get some more refills and be carefull, the fibre waste can be dangerous.
The vinegar method is helpfull for the very large pieces you sometimes get (that was the reason for this topic in the first place), for the smaller pieces I find it very usefull to simple coat them with a dull coat of clear, it also helps to give to ca glue something to hold on to. Don't use gloss, the idea is to create an uneven suface